Controllable Synthesis of Ultrathin NiCo₂O₄ Nanosheets Incorporated onto Composite Nanotubes for Efficient Oxygen Reduction

Controllable Synthesis of Ultrathin NiCo₂O₄ Nanosheets Incorporated onto Composite Nanotubes for Efficient Oxygen Reduction. Yunpeng Huang, Fen Cui, Yan Zhao, Jian Bao, Jiabiao Lian, Yuanguo Xu, Tianxi Liu*, and Huaming Li*. Chem. Asian J. 2017, 12, 2426-2433.

Abstract: Exploring non-precious-metal-based oxygen reduction reaction (ORR) electrocatalysts featuring high efficiency, low cost, and environmental friendliness is of great importance for the broad applications of fuel cells and metal–air batteries. In this work, ultrathin NiCo₂O₄ nanosheets deposited on 1D SnO₂ nanotubes (SNT) were successfully fabricated through a productive electrospinning technique followed by a sintering and low-temperature coprecipitation strategy. This hierarchically engineered architecture has ultrathin NiCo₂O₄ nanosheets uniformly and fully erected on both walls of tubular SNTs, which results in improved electrochemical activity as an ORR catalyst, in terms of positive onset potential and high current density, as well as superior tolerance to crossover effects and long-term durability with respect to the commercial Pt/C catalyst. The excellent performance of SNT@NiCo₂O₄ composites may originate from their rationally designed hierarchical tubular nanostructure with completely exposed active sites and interconnected 1D networks for efficient electron and electrolyte transfer; this makes these composite nanotubes promising candidates to replace platinum-based catalysts for practical fuel cell and metal-air battery applications.